Abstract
Aiming at improved classification of crude oils, naphthalene and phenanthrene isomerization and dealkylation processes were considered in detail as a possible basis to select new maturation parameters. Crude oils originating from the Banat depression (Southeastern Pannonian Basin, Serbia) were used as objects of our study. Four new maturation parameters are proposed in this paper. Two of them are based on dimethylnaphthalene (DMN) and trimethylnaphthalene (TMN) isomerization reactions: DNx = (1,3-DMN + 1,6-DMN)/(1,4-DMN + 1,5-DMN) and TNy = (1,3,6-TMN + 1,3,7-TMN)/(1,3,5-TMN + 1,4,6-TMN). The other two are based on demethylation of dimethyl-and trimethylphenanthrenes (DMP and TMP) into corresponding methylphenanthrenes (MP): MDR = ΣMP/ΣDMP and MTR = ΣMP/ΣTMP. The new parameters’ advantageous applicability was demonstrated by factor analysis, comparing them with maturation parameters known from literature.
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References
K. E. Peters and J. M. Moldowan, Biomarker Guide (Prentice Hall, Englewood Cliffs, 1993).
W. K. Seifert and J. M. Moldowan, “Applications of Steranes, Terpanes and Mono-Aromatics to the Maturation, Migration and Source of Crude Oils,” Geochim. Cosmochim. Acta 42, 77–95 (1978).
M. Radke, D. H. Welte, and H. Willsch, “Geochemical Study on a Well in the Western Canada Basin: Relation of the Aromatic Distribution Pattern to Maturity of Organic Matter,” Geochim. Cosmochim. Acta 46, 1–10 (1982).
M. Radke, H. Willsch, D. Leythaeuser, and M. Teichmuller, “Aromatic Components of Coal: Relation of Distribution Pattern to Rank,” Geochim. Cosmochim. Acta 46, 1831–1848 (1982).
M. Radke, “Organic Geochemistry of Aromatic Hydrocarbons,” in Advances in Petroleum Geochemistry, Ed. by J. Brooks and D. Welte (Academic, London, 1987), pp. 141–205.
M. G. Strachan, R. Alexander, and R. I. Kagi, “Trimethylnapthalenes in Crude Oils and Sediments: Effects of Source and Maturity,” Geochim. Cosmochim. Acta 52, 1255–1264 (1988).
R. Alexander, R. I. Kagi, S. J. Rowland, et al., “The Effects of Thermal Maturity on Distributions of Dimethylnaphthalenes and Trimethyl-Naphthalenes in Some Ancient Sediments and Petroleums,” Geochim. Cosmochim. Acta 49, 385–395 (1985).
R. Alexander, R. I. Kagi, R. K. Singh, and I. B. Sosrowidjojo, “The Effect of Maturity on the Relative Abundances of Cadalene and Isocadalene in Sediments from the Gippsland Basin, Australia,” Org. Geochem. 21, 115–120 (1994).
A. Shimoyama, H. Masayosi, and N. Shinya, “Naphthalenes in Neogene Sediments of the Shinjo Basin, Japan,” Geochem. J. 34, 333–340 (2000).
D. Botor, M. Kotarba, and P. Kosakowski, “Petroleum Generation in the Carboniferous Strata of the Lublin Trough (Poland): An Integrated Geochemical and Numerical Modelling Approach,” Org. Geochem. 33, 461–476 (2002).
D.-J. H. Simons, F. Kenig, and C. J. Schroder-Adams, “An Organic Geochemical Study of Cenomanian-Turonian Sediments from the Western Interior Seaway, Canada,” Org. Geochem. 34, 1177–1198 (2003).
W. Püttman and H. Villar, “Occurrence and Geochemical Significance of 1.2,5.6-Tetramethylnaphthalene,” Geochim. Cosmochim. Acta 51, 3023–3029 (1987).
R. K. Singh, R. Alexander, and R. I. Kagi, “Identification and Occurrence of Norcadalenes and Related Compounds in Crude Oils and Sediments,” Org. Geochem. 21, 249–256 (1994).
A. Golovko and G. Pevneva, “Oil Families of West Siberia in Accordance with Alkylnaphthalenes Composition,” in Abstracts of 21st International Meeting on Organic Geochemistry, Krakow, September 8–12, 2003 (GEOSPHERA, 2003), pp. 73–74.
J. K. Volkman, “Biodegradation of Aromatic Hydrocarbons in Crude Oils from the Barrow Sub-Basin of Western Australia,” Org. Geochem. 6, 619–632 (1984).
S. J. Fisher, R. Alexander, and R. I. Kagi, “Biodegradation of Aromatic Hydrocarbons in Sediments Adjacent to an Off-Shore Petroleum Development and Production Platform,” Polycyc. Arom. Comp. 9, 257–264 (1995).
S. J. Fisher, R. Alexander, and R. I. Kagi, “Biodegradation of Alkylnaphthalenes in Sediment Adjacent to an Off-Shore Petroleum Production Platform,” Polycyc. Arom. Comp 11, 35–42 (1996).
K. Grice, S. J. Fisher, R. Trolio, et al., “Changes in the Molecular Composition of a Condensate with Increasing Biodegradation in Intertidal Coastal Sediments,” in Abstracts of 19th International Meeting on Organic Geochemistry, Istanbul, September 6–10, 1999 (TÜBITAK, Istanbul, 1999), pp. 359–360.
A. Golovko and V. Ivanov, “Changes in Triarene Composition on the Oil Filtration through Various Minerals,” in Abstracts of 19th International Meeting on Organic Geochemistry, Istanbul, September 6–10, 1999 (TÜBITAK, Istanbul, 1999), pp. 585–586.
B. G. K. van Aarssen, T. P. Bastow, R. Alexander, and R. I. Kagi, “Distributions of Methylated Naphthalenes in Crude Oils: Indicators of Maturity, Biodegradation and Mixing,” Org. Geochem. 30, 1213–1227 (1999).
R. Alexander, R. I. Kagi, and A. V. Larcher, “Clay Catalysis of Aromatic Hydrogen-Exchange Reactions,” Geochim. Cosmochim. Acta 46, 219–222 (1982).
R. Alexander, R. I. Kagi, A. V. Larcher, and G. W. Woodhouse, “Aromatic Hydrogen Exchange in Petroleum Source Rocks,” in Advances in Organic Geochemistry 1981, Ed. by M. Bjoroy et al. (Wiley, New York, 1983), pp. 69–71.
A. G. Requejo, R. Sassen, T. McDonald et el, “Polynuclear Aromatic Hydrocarbons (PAH) as Indicators of the Source and Maturity of Marine Crude Oils,” Org. Geochem. 24, 1017–1033 (1996).
M. Radke, H. Willsch, and D. H. Welte, “Maturity Parameters Based on Aromatic Hydrocarbons: Influence of the Organic Matter Type,” Org. Geochem. 10, 51–63 (1986).
A. G. Requejo, “Maturation of Petroleum Source Rocks-II. Quantitative Changes in Extractable Hydrocarbon Content and Composition Associated with Hydrocarbon Generation,” Org. Geochem. 21, 91–105 (1994).
S. R. Yawanarajah and M. A. Kruge, “Lacustrine Shales and Oil Shales from Stellarton Basin, Nova Scotia, Canada: Organofacies Variations and Use of Polyaromatic Hydrocarbons as Maturity Indicators,” Org. Geochem. 21, 153–170 (1994).
F. H. Abdullah and J. Connan, “Geochemical Study of Some Cretaceous Rocks from Kuwait: Comparison with Oils from Cretaceous and Jurassic Reservoirs,” Org. Geochem. 33, 125–148 (2002).
A. Wilhelms, N. Telnæs, A. Steen, and J. Augustson, “A Quantitative Study of Aromatic Hydrocarbons in a Natural Maturity Shale Sequence—The 3-Methyl-Phenanthrene/Retene Ratio, a Pragmatic Maturity Parameter,” Org. Geochem. 29, 97–105 (1998).
A. K. Golovko, Doctoral Dissertation in Geology and Mineralogy, University of Tomsk (1997).
M. Radke and D. H. Welte, “The Methylphenanthrene Index (MPI): A Maturity Parameter Based on Aromatic Hydrocarbons,” in Advances in Organic Geochemistry 1981, Ed. by M. Bjoroy et al. (Wiley, New York, 1983), pp. 504–512.
J. W. Smith, S. C. George, and B. D. Batts, “The Geosynthesis of Alkylaromatics,” Org. Geochem. 23, 71–80 (1995).
V. Ivanov and A. K. Golovko, “Phenanthrene Hydrocarbons in USSR Crude Oils,” Sib. Chem. J., No. 1, 94–102 (1992).
K. Stojanović, B. Jovančićević, G. S. Pevneva, et al. “Maturity Assessment of Oils from the Sakhalin Oil Fields in Russia: Phenanthrene Content as a Tool,” Org. Geochem. 32, 721–731 (2001).
M. D. Belonin, V. N. Golubeva, and G. T. Skublov, Principal Component Analysis in Geology (Nauka, Moscow, 1982) [in Russian].
C. Reimann, P. Filmoser, and R. G. Garrett, “Factor Analysis Applied to Regional Geochemical Data: Problems and Possibilities,” Appl. Geochem. 17(3), 85–206 (2002).
M. Ercegovac, in Petroleum geology (Belgrade, RGF and DIT NIS-Naftagas, 2002), pp. 380–397 [in Serbian].
M. Šaban, S. B. Jovančićević, S. Saračević, et al. “Correlative Geochemical Study of Crude Oils from Southeastern Part of the Pannonian Basin,” Org. Geochem. 13, 325–333 (1988).
B. Jovančićević, P. Polić, and D. Vitorovi, “Organic Geochemical Investigation of Crude Oils. The Southeastern Part of the Pannonian Basin in Yugoslavia,” J. Serb. Chem. Soc. 63, 397–418 (1998).
M. Šaban, S. B. Jovančićević, T. Glumičić, and S. Saračević, “Organic Geochemical Study of the “W” Oil-Gas Field in the Yugoslav Part of the Pannonian Basin,” Org. Geochem. 16, 477–488 (1990).
B. JoJovančićevićj, Tasić, P. Polić, et al. “GC-MS in Oil Correlation Studies—Effects of Biodegradation on Sterane and Terpane Maturation Parameters,” J. Serb. Chem. Soc. 61, 817–821 (1996).
M. Šaban, S. B. Jovančićević, T. Glumičić, and N. Dogovi, “Oil-Oil Correlation Based on Gas Chromatographic-Mass Spectrometric Analysis of Polycyclic Biomarkers,” Rapid Communications in Mass Spectrometry 4, 505–509 (1990).
K. Stojanovi, B. Jovančićević, J. A. Golovko, et al., “New Di-and Trimethylnaphthalene Parameters for the Evaluating the Thermal Maturity of Oils from South-Eastern Part of Pannonian Basin (Serbia),” in Proceedings of 5th International Conference on Oil and Gas Chemistry, Tomsk, Russia, September 22–26 2003 (2003), pp. 23–26 [in Russian].
B. Jovančićević, M. Šaban, T. Glumičić, et al., “Correlation of Some Southeast Pannonian Basin Oils Based on Carbon Isotopes, Compositions and Hydrocarbon Biomarkers,” J. Serb. Chem. Soc. 57, 391–405 (1992).
B. Jovančićević, H. Wehner, G. Scheeder, et al., “An Organic Geochemical Correlation Study of Some Drmno Depression Crude Oils (Southern Part of the Pannonian Basin, Yugoslavia),” J. Serb. Chem. Soc. 66, 297–308 (2001).
F. Horváth, “Towards a Mechanical Models for the Formation of the Pannonian Basin,” Tectonophysics 226, 333–357 (1993).
C. S. Sajgó, Z. A. Horváth, and J. Lefler, “An Organic Maturation Study of the Hod-I Borehole (Pannonian Basin),” in The Pannonian Basin—A Study in Basin Evolution, Ed. by L. Royden and F. Horvath (Tulsa-Oklahoma-Budapest, AAPG Memoir, 1988), pp. 297–309.
F. Horváth, “Phases in Compression during the Evolution of the Pannonian Basin and Its Bearing on Hydrocarbon Exploration,” Marine Petrol. Geol. 12, 837–844 (1995).
M. Ercegovac, A. Kostić, H. Karg, et al. “Temperature and Burial History Modelling of the Drmno and Markovac Depressions, SE Pannonian Basin, Serbia,” Petrol. Geol. 26, 5–27 (2003).
M. Ercegovac and A. Kostić, “The Thermal Maturity of Kerogen and Geothermics of Neogene Sediments in the Drmno Depression (Serbia),” Ann. Geol. Peninsule Balkanique 57, 331–356 (1993).
M. Ercegovac and A. Kostić, “The Kerogen Maturity of the Neogene Sediments in the Drmno Depression (Kostolac, Serbia),” J. Serb. Chem. Soc. 61, 1063–1069 (1996).
M. Ercegovac, A. Grubić, I. Dokovi, et al. “Contribution to Better Understanding of Geological and Geochemical Properties Characterizing Drmno Depression (Serbia) from the Aspect of Oil-Gas Potential,” Ann. Geol. Peninsule Balkanique 57, 373–393 (1993).
M. Ercegovac, M. Jeremić, and S. Daji, “Miocene Sedimentary Organic Facies and Palynofacies in Drmno Depression (Serbia),” Ann. Geol. Peninsule Balkanique 61, 143–165 (1997).
V. Ivanov, O. S. Andrienko, and A. K. Golovko, “Triarene Isolation from Crude Oils for Geochemical Investigation,” Geokhimiya, No. 3, 91–94 (1991).
K. G. Jöreskog, J. E. Klovan, and R. A. Reyment, Methods in Geomathematics I, Geological Factor Analysis (Elsevier, Oxford, 1976).
M. L. Angelin, A. Collignan, J. Bellocq, et al., “Investigation of Polycyclic Aromatic Hydrocarbons in Source Rock Bitumens and Petroleums by High Pressure Liquid Chromatography,” C. R. Acad. Sci., Ser. II 296, 705–708 (1983).
R. Alexander, R. I. Kagi, and P. N. Sheppard, “1.8-Dimethylnapthalene as Indicator of Petroleum Maturity,” Nature 308, 442–443 (1984).
R. Ishiwatari and K. Fukushima, “Generation of Unsaturated and Aromatic Hydrocarbons by Thermal Alteration of Young Kerogen,” Geochim. Cosmochim. Acta 43, 1343–1349.
K. Stojanovi, New Approaches in the Investigation of Crude Oil Maturity on the Basis of Polycyclic Saturated and Aromatic Hydrocarbon Distributions,” Dr. Sci. Thesis (University of Belgrade, 2004) [in Serbian].
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Stojanović, K., Jovančićević, B., Vitorovi, D. et al. New maturation parameters based on naphthalene and phenanthrene isomerization and dealkylation processes aimed at improved classification of crude oils (Southeastern Pannonian Basin, Serbia). Geochem. Int. 45, 781–797 (2007). https://doi.org/10.1134/S0016702907080058
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DOI: https://doi.org/10.1134/S0016702907080058